

You can start with used but modern x86 - the n100 line - has very low power usage and will long term be a better investment. A pi is about the same cost once you get the accessories needed and uses as much power to get work done, but can do less work. (If the computers are idel the pi wins)



FreeBSD - it won’t be easy, but I’ve been a BSD guy at heart for decades… You will learn a lot and eventually be able to create better systems, but it will be years before you should risk putting anything important on a system - as a noob you have a lot to learn the hard way. Once you think you know FreeBSD you should try the other BSDs, and things like gentoo linux: you will really learn how this works.
You can follow the advice of the others and get a system going sooner. It isn’t a wrong choice, but you won’t learn as much and if something doesn’t work the way you want you are stuck since you can’t dare change anything. As such I have to advice against it despite all the time/effort my advice will cost you.